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Na3GaF6 - A crystal chemical and solid state NMR spectroscopic study

Author:
Boehnisch, David  Seidel, Stefan  Benndorf, Christopher  Jansen, Thomas  Funke, Lena  Hoffmann, Rolf-Dieter  Heletta, Lukas  Stahl, Juliane  Johrendt, Dirk  Eckert, Hellmut  Juestel, Thomas  Poetgen, Rainer  


Journal:
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS


Issue Date:
2018


Abstract(summary):

Na3GaF6 and Na3GaF6:Mn4+ samples were obtained from NaNO3 and Ga(NO3)(3)center dot 9H(2)O in hydrofluoric acid using K2MnF6 or NaMnO4 as manganese sources. The structure of Na3GaF6 was studied by single crystal X-ray diffraction at 90, 293, 440 and 500 K, confirming the monoclinic cryolite type structure, space group P2(1)/c. The gallium atoms show slightly distorted octahedral coordination by fluorine atoms, similar to the Nal atoms. Coordination number 8 is observed for Na2. Both sodium sites are clearly distinguished by Na-23 MAS-NMR spectroscopy. Above 400 K the spectra reveal distinct chemical exchange effects, signifying sodium ion hopping between these two sites. At the same time static F-19 NMR spectra indicate pronounced motional narrowing effects in this temperature region. The nearly invariant Ga-69 MAS-NMR spectra suggest that any reorientational motion involving the GaF63- ions (if present) occurs with preservation of the center of mass of these octahedra.


Page:
479---487


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