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Solution-Processed C-60 Single-Crystal Field-Effect Transistors

Author:
Kang, Woogun  Kitamura, Masatoshi  Itoh, Tetsuji  Arakawa, Yasuhiko  


Journal:
JAPANESE JOURNAL OF APPLIED PHYSICS


Issue Date:
2012


Abstract(summary):

We have demonstrated high mobility C-60 single-crystal field-effect transistors formed by a solution process. 1,2,4-Trichlorobenzene (TCB) C-60 solution formed plate like crystals with sizes exceeding 500 mu m. We found that the C-60 single crystals prepared from solution consist of two TCB molecules per C-60 molecule, with a triclinic crystal structure. TCB molecules in C-60 crystals are extracted by an annealing process, and the crystal structure was changed to a face-centered-cubic structure. The C-60 single crystal prepared from TCB solution showed typical n-channel operation and high electron mobilities of up to 1.4 cm2 V-1 s(-1). (C) 2012 The Japan Society of Applied Physics


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