Reduction of magnetic hysteresis loss in La(0.5)Pr(0.5)Fe(11.4)Si(1.6)H(x) hydrides with large magnetocaloric effects RID G-6874-2011

Author:

Zhao, Jin-liang  Shen, Jun  Hu, Feng-xia  Li, Yang-xian  Sun, Ji-rong  Shen, Bao-gen  

Journal:

JOURNAL OF APPLIED PHYSICS

Issue Date:

2010

Abstract(summary):

Magnetic properties and magnetocaloric effects (MCEs) have been investigated in hydrogenated La(0.5)Pr(0.5)Fe(11.4)Si(1.6)H(x) (x=0, 0.9, and 1.6) compounds. It is found that the Curie temperature T(C) can be tuned from 189 to 317 K by adjusting hydrogen content from 0 to 1.6. It is attractive that both thermal and magnetic hysteresis are remarkably reduced because of the weakness of the itinerant-electron metamagnetic transition after hydrogenation, while the large magnetic entropy change is retained. The maximal hysteresis loss at T(C) decreases from 17.8 to 2.3 J/kg as x increases from 0 to 1.6. For the samples with x=0, 0.9, and 1.6, the maximal values of -Delta S are 26.3, 24.1, and 22.1 J/kg K at T(C), with efficient refrigeration capacities of 463, 366, and 351 J/kg for a field change of 0-5 T, respectively. Large reversible MCE and small hysteresis with considerable value of refrigeration capacity indicate the potentiality of La(0.5)Pr(0.5)Fe(11.4)Si(1.6)H(x) hydrides as a candidate magnetic refrigerant around room temperature. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3374635]