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Cascade Cross-Coupling of Dienes: Photoredox and Nickel Dual Catalysis

Author:
Huang, Long  Zhu, Chen  Yi, Liang  Yue, Huifeng  Kancherla, Rajesh  Rueping, Magnus  


Journal:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION


Issue Date:
2020


Abstract(summary):

Chemical transformations based on cascade reactions have the potential to simplify the preparation of diverse and architecturally complex molecules dramatically. Herein, we disclose an unprecedented and efficient method for the cross-coupling of radical precursors, dienes, and electrophilic coupling partners via a photoredox- and nickel-enabled cascade cross-coupling process. The cascade reaction furnishes a diverse array of saturated carbo- and heterocyclic scaffolds, thus providing access to a quick gain in C-C bond saturation.


Page:
457---464


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