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Deaminative Reductive Arylation Enabled by Nickel/Photoredox Dual Catalysis.

Journal:
Organic letters


Issue Date:
2019


Abstract(summary):

Described is a cross-electrophilic, deaminative coupling strategy harnessing Katritzky salts as a new species of electrophile in Ni/photoredox dual catalytic reductive cross-coupling reactions. Distinguishing features of this arylation protocol include its mild reaction conditions, high chemoselectivity, and adaptability to a variety of complex substrates [i.e., pyridinium salts derived from amines and partners derived from (hetero)aryl bromides].=20


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