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Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions

Author:
Lin, Jinqiang  Zou, Chao  Zhang, Xiaobao  Gao, Qin  Suo, Sa  Zhuo, Qihang  Chang, Xiaoyong  Xie, Mo  Lu, Wei  


Journal:
DALTON TRANSACTIONS


Issue Date:
2019


Abstract(summary):

Dinuclear pincer-type cyclometalated Pd(ii) complexes with foldable diacetylide ligands show crystallographically determined intramolecular PdMIDLINE HORIZONTAL ELLIPSISPd contacts of 3.203-3.380 angstrom. In deoxygenated fluid solutions, these Pd(ii) complexes are highly phosphorescent in the red region with emission quantum yields up to 48%, which has been ascribed to metal-metal-to-ligand charge-transfer (MMLCT) excited states in nature.


Page:
10417---10421


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