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Allylation of aldehydes by dual photoredox and nickel catalysis

Author:
Gualandi, Andrea  Rodeghiero, Giacomo  Faraone, Adriana  Patuzzo, Filippo  Marchini, Marianna  Calogero, Francesco  Perciaccante, Rossana  Jansen, Thomas Paul  Ceroni, Paola  Cozzi, Pier Giorgio  


Journal:
CHEMICAL COMMUNICATIONS


Issue Date:
2019


Abstract(summary):

Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(II) complex, [Ru(bpy)(3)](2+) as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.


Page:
6838---6841


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