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Chirality-Economy Catalysis:Asymmetric Transfer Hydrogenation of Ketones by Ru-Catalysts of Minimal Stereogenicity

Author:
Chen, Fumin  He, Dongxu  Chen, Li  Chang, Xiaoyong  Wang, David Zhigang  Xu, Chen  Xing, Xiangyou  


Journal:
ACS CATALYSIS


Issue Date:
2019


Abstract(summary):

This manuscript describes the design and synthesis of Ru catalysts that feature only a single stereogenic element, yet this minimal chirality resource is demonstrated to be competent for effecting high levels of stereoinduction in the asymmetric transfer hydrogenation over a broad range of ketone substrates, including those that are not accommodated by known catalyst systems. The single stereogenic center of the (1-pyridine-2-yl)methanamine) is the only point-chirality in the catalysts, which simplifies this catalyst system relative to existing literature protocols.


Page:
5562---5566


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