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Preparation and capacitive properties of lithium manganese oxide intercalation compound

Author:
Tian, Fang  Xie, Yibing  


Journal:
JOURNAL OF NANOPARTICLE RESEARCH


Issue Date:
2015


Abstract(summary):

Lithium manganese oxide intercalation compound (Li0.7MnO2) supported on titanium nitride nanotube array (TiN NTA) was applied as cathode electrode material for lithium-ion supercapacitor application. Li0.7MnO2/TiN NTA was fabricated through electrochemical deposition and simultaneous intercalation process using TiN NTA as a substrate, Mn(CH3-COO)(2) as manganese source, and Li2SO4 as lithium source. The morphology and microstructure of the Li0.7MnO2/TiN NTA were characterized by scanning electron microscopy and X-ray diffraction analysis. The electrochemical performance of the Li0.7MnO2/TiN NTA was investigated by electrochemical impedance spectroscopy, cyclic voltammetry, and galvanostatic charge/discharge measurements. Li0.7MnO2/TiN NTA exhibited higher capacitive performance in Li2SO4 electrolyte solution rather than that in Na2SO4 electrolyte solution, which was due to the different intercalation effects of lithium-ion and sodium-ion. The specific capacitance was improved from 503.3 F g(-1) for MnO2/TiN NTA to 595.0 F g(-1) for Li0.7MnO2/TiN NTA at a current density of 2 A g(-1) in 1.0 MLi2SO4 electrolyte solution, which was due to the intercalation of lithium-ion for Li0.7MnO2. Li0.7MnO2/TiN NTA also kept 90.4 % capacity retention after 1000 cycles, presenting a good cycling stability. An all-solid-state lithium-ion supercapacitor was fabricated and showed an energy density of 82.5 Wh kg(-1) and a power density of 10.0 kW kg(-1).


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