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C(sp(3))-F,C(sp(2))-F and C(sp(3))-H bond activation at silicon(II) centers

Author:
Swamy, V. S. V. S. N.  Parvin, Nasrina  Raj, K. Vipin  Vanka, Kumar  Sen, Sakya S.  


Journal:
CHEMICAL COMMUNICATIONS


Issue Date:
2017


Abstract(summary):

Silylene [PhC(NtBu)(2)SiN(SiMe3)(2)] (1) cleaves the C(sp(3))-H and C-F bonds of acetophenone and 1,1,1-trifluoroacetophenone, respectively, under mild conditions. The reaction is initiated via a nucleophilic attack from the oxygen to the silicon atom followed by C-F/H bond cleavage. The scope of C-F bond activation has further been extended with C6F6 and C6F5CF3.


Page:
9850---9853


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