Enantioselective divergent total syntheses of (+)-fawcettimine, (+)-fawcettidine, (+)-lycoflexine, (+)-lycoposerramine Q, (-)-Huperzine Q and (+)-N-oxyhuperzine Q have been described from a common precursor. The syntheses feature a vinylogous Rubottom oxidation and several biomimetic transformations. (C) 2014 Elsevier Ltd. All rights reserved.
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