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Synthesis and hydrogen absorption kinetics of V4Cr4Ti alloy

Author:
Kumar, Sanjay   Taxak, Manju   Krishnamurthy, Nagaiyar  


Journal:
Journal of Thermal Analysis and Calorimetry


Issue Date:
2013


Abstract(summary):

V4Cr4Ti alloy is synthesized by aluminothermy process followed by electron beam refining. Hydrogen absorption characteristics of the alloy have been evaluated by measuring the pressure composition isotherm (PCIT) at 57 A degrees C temperature. Two plateau pressures are observed in the PCIT curve. Substantial decrease in the hydrogen absorption capacity of the alloy as compared to vanadium has been recorded. Hydrogen absorption kinetics of the alloy was investigated in the temperature range of 200-500 A degrees C. Three-dimensional diffusion appears to be the rate controlling step of the hydrogen absorption. The apparent activation energy was calculated as 0.16 eV/atom-hydrogen.


Page:
51-57


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