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Compressibility of C61D2 up to 1 GPa in the temperature range 175-345 K RID F-1026-2010

Author:
Lundin, A  Soldatov, A  Sundqvist, B  Strongin, RM  Brard, L  Fischer, JE  Smith, AB  


Journal:
CARBON


Issue Date:
1996


Abstract(summary):

We have measured the bulk modulus K for C61D2 up to 1 GPa in the temperature range 175-343 K. For face-centered cubic C61D2 above 290 K, we find an anomalously low value for K below about 0.15 GPa, possibly indicating pressure-induced changes in the structure. The (extrapolated) zero-p bulk modulus K(0) decreases with increasing T from 6.7 GPa at 175 K to 5.2 GPa at 343 K. A comparison with hypothetical expanded f.c.c. C-60 with the same lattice constant shows that K(0) values are similar, indicating that the main intermolecular interactions are still between molecular bellies, not the sidegroups. Copyright (C) 1996 Elsevier Science Ltd


Page:
1119---1121


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