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Synthesis of monohydric alcohols from CO and H(2) on Fe/Sibunit catalysts

Author:
Krylova, A. Yu  Kurkin, V. I.  Kulikova, M. V.  Lyadov, A. S.  Sagitov, S. A.  


Journal:
SOLID FUEL CHEMISTRY


Issue Date:
2011


Abstract(summary):

It was demonstrated that R (2)-R (4) saturated monohydric alcohols can be synthesized from CO and H(2) in the presence of Fe catalysts containing a carbon support of the Sibunit type with granule sizes of 3-5, 1-2, and 0.05-0.1 mm in a fixed-bed reactor at 3 MPa and 240-300A degrees C. It was found that the activity of Fe/Sibunit catalysts and their selectivity for the formation of liquid synthetic products increased with the size of granules and the amount of iron. The catalysts make it possible to obtain fatty alcohols, in which the fraction of R (2)-R (4) alcohols is as high as 75%, in yields to 56 g/m(3).


Page:
281---285


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