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Design and Synthesis of Oligoamide-Based Double -Helix Mimetics

Author:
Kulikov, Oleg V.  Thompson, Sam  Xu, Hai  Incarvito, Christopher D.  Scott, Richard T. W.  Saraogi, Ishu  Nevola, Laura  Hamilton, Andrew D.  


Journal:
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY


Issue Date:
2013


Abstract(summary):

An extensive series of bis-oligobenzamides and bis-oligopyridylamides have been efficiently prepared and studied by X-ray analysis and computational methods. A modular synthesis led to double -helix mimics bearing between two and ten branched side-chains. The inter-helix angle and distance can be tuned by varying the length and rigidity of the spacer, thereby reproducing the recognition domains of a range of super-secondary structures.


Page:
3433---3445


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