Creat membership Creat membership
Sign in

Forgot password?

Confirm
  • Forgot password?
    Sign Up
  • Confirm
    Sign In
Creat membership Creat membership
Sign in

Forgot password?

Confirm
  • Forgot password?
    Sign Up
  • Confirm
    Sign In
Collection
For ¥0.57 per day, unlimited downloads CREATE MEMBERSHIP Download

toTop

If you have any feedback, Please follow the official account to submit feedback.

Turn on your phone and scan

home > search >

Orbital alignment in N2O photodissociation. I. Determination of all even rank anisotropy parameters

Author:
Smolin, AG  Vasyutinskii, OS  Wouters, ER  Suits, AG  


Journal:
JOURNAL OF CHEMICAL PHYSICS


Issue Date:
2004


Abstract(summary):

We present a general method for determination of the photofragment K=4 state multipoles in an ion imaging experiment. These multipoles are important for determining the full density matrix for any photofragment with j(a)greater than or equal to2. They are expressed in terms of laboratory frame anisotropy parameters that have distinct physical origins and possess characteristic angular distributions. The explicit expression for the (2+1) resonant multiphoton ionization absorption signal for the case of arbitrarily polarized probe light is derived and a procedure for isolation of the rank-4 state multipoles from all others is shown. This treatment is applied to the case of O(D-1) produced in the 193 nm photodissociation of N2O. The results show nonzero values for all K=4 anisotropy parameters, indicating the complexity of the photodissociation dynamics in this system. (C) 2004 American Institute of Physics.


Page:
6759---6770


VIEW PDF

The preview is over

If you wish to continue, please create your membership or download this.

Create Membership

Similar Literature

Submit Feedback

This function is a member function, members do not limit the number of downloads